Dataset Open Access

Data publication: Bubble-induced versus thermodynamic voltage losses during pressurized alkaline water electrolysis

Rox, Hannes; Liang, Feng; Baumann, Robert; Marzec, Mateusz M.; Sokołowski, Krystian; Yang, Xuegeng; Lasagni, Andrés F.; van de Krol, Roel; Eckert, Kerstin


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{
  "name": "Data publication: Bubble-induced versus thermodynamic voltage losses during pressurized alkaline water electrolysis", 
  "inLanguage": {
    "alternateName": "eng", 
    "@type": "Language", 
    "name": "English"
  }, 
  "datePublished": "2026-03-27", 
  "keywords": [
    "Alkaline water electrolysis", 
    "Pressurized electrolysis", 
    "Hydrogen evolution reaction", 
    "Bubble dynamics", 
    "Direct laser writing"
  ], 
  "description": "<p>Understanding how bubbles influence the efficiency of water electrolysis is crucial to achieve economically competitive hydrogen, generated by renewable energy sources, such as wind and solar power. Water electrolysis is typically performed at high pressures to &nbsp;lower the cost of the energy-intensive mechanical compression required for the produced hydrogen. Thus, a better understanding of how absolute pressure affects electrochemical performance and bubble size is necessary.&nbsp; This data set compares four laser-structured Ni electrodes with different spatial periods (<strong>&Lambda; = 30, 40, 60, and 100 &mu;m</strong>) at a constant depth of <strong>&asymp;&nbsp;7 &mu;m</strong>. The comparison is made in terms of electrode potential, detached bubble size, and the number of nucleation sites. The applied current density was varied between<em> </em><strong><em>j </em>= -25, -50, and -100 mA/cm&sup2;</strong>, and the absolute cell pressure was varied between <strong><em>p</em> = 1, 2, 4, and 6 bar</strong>. The electrolyte used was <strong>1 M KOH</strong>. All experiments were carried out at a constant temperature of <strong>T = 293 K</strong>.</p>\n\n<p><strong>A.) Description of <em>Data.zip</em>:</strong></p>\n\n<p>An overview of all performed experiments is given in the file <strong><em>Summary.csv</em></strong>. The data is analyzed as described in the corresponding journal publication <em><strong>Bubble-induced versus thermodynamic voltage losses&nbsp;during pressurized alkaline water electrolysis</strong></em>. Each data set is stored in a .hdf5-file, with the relevant metadata incorporated into the attributes assigned to the groups/datasets within the .hdf5-file. The data files are structured in groups as follows:</p>\n\n<ul>\n\t<li>Electrochemical Measurement Data\n\t<ul>\n\t\t<li>Galvanostatic Measurement Data</li>\n\t</ul>\n\t</li>\n\t<li>Results\n\t<ul>\n\t\t<li>Detected Bubbles Frontview</li>\n\t</ul>\n\t</li>\n\t<li><em>Frontview Raw Images (only for <strong>LS_P_01.hdf5</strong>)</em></li>\n</ul>\n\n<p>With the exception of a single comprehensive data set comprising unprocessed images (<strong>LS_P</strong><strong>_01.hdf5</strong>), the remaining raw images from all performed measurements can be made available upon request.</p>\n\n<p><strong>B.) Description of <em>Videos.zip</em>:</strong></p>\n\n<p>Example videos of non-structured and laser-structured electrodes at a current density of <strong>-100 mA/cm&sup2;</strong> are provided. The characteristic videos provided are named according to the following scheme:</p>\n\n<ul>\n\t<li><em>SpatialPeriod_Pressure_CurrentDensity</em></li>\n\t<li><em>E.g.: </em>100&mu;m_6bar_-100mAcm-2</li>\n</ul>", 
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      "@type": "DataDownload"
    }, 
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      "fileFormat": "csv", 
      "contentUrl": "https://rodare.hzdr.de/api/files/e856cf46-68fe-4d67-9f4f-9262e9802b3b/Summary.csv", 
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      "contentUrl": "https://rodare.hzdr.de/api/files/e856cf46-68fe-4d67-9f4f-9262e9802b3b/Videos.zip", 
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  "@context": "https://schema.org/", 
  "url": "https://rodare.hzdr.de/record/4547", 
  "license": "https://creativecommons.org/licenses/by/4.0/legalcode", 
  "sameAs": [
    "https://www.hzdr.de/publications/Publ-43192"
  ], 
  "@type": "Dataset", 
  "creator": [
    {
      "@id": "https://orcid.org/0000-0003-2826-6903", 
      "affiliation": "Institute of Fluid Dynamics, Helmholtz-Zentrum Dresden-Rossendorf, 01328 Dresden, Germany", 
      "@type": "Person", 
      "name": "Rox, Hannes"
    }, 
    {
      "@id": "https://orcid.org/0000-0002-7131-8230", 
      "affiliation": "School of Mechanical Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi 710049, China", 
      "@type": "Person", 
      "name": "Liang, Feng"
    }, 
    {
      "@id": "https://orcid.org/0000-0002-8589-4685", 
      "affiliation": "Institute of Manufacturing, TU Dresden, 01062 Dresden, Germany", 
      "@type": "Person", 
      "name": "Baumann, Robert"
    }, 
    {
      "@id": "https://orcid.org/0000-0001-9834-3930", 
      "affiliation": "Academic Centre for Materials and Nanotechnology, AGH University of Krakow, 30-059 Krakow, Poland", 
      "@type": "Person", 
      "name": "Marzec, Mateusz M."
    }, 
    {
      "@id": "https://orcid.org/0000-0001-8576-2191", 
      "affiliation": "Academic Centre for Materials and Nanotechnology, AGH University of Krakow, 30-059 Krakow, Poland", 
      "@type": "Person", 
      "name": "Soko\u0142owski, Krystian"
    }, 
    {
      "@id": "https://orcid.org/0000-0002-4617-0713", 
      "affiliation": "Institute of Fluid Dynamics, Helmholtz-Zentrum Dresden-Rossendorf, 01328 Dresden, Germany", 
      "@type": "Person", 
      "name": "Yang, Xuegeng"
    }, 
    {
      "@id": "https://orcid.org/0000-0003-4333-4636", 
      "affiliation": "Institute of Manufacturing, TU Dresden, 01062 Dresden, Germany", 
      "@type": "Person", 
      "name": "Lasagni, Andr\u00e9s F."
    }, 
    {
      "@id": "https://orcid.org/0000-0003-4399-399X", 
      "affiliation": "Institute for Solar Fuels, Helmholtz-Zentrum f\u00fcr Materialien und Energie GmbH, 14109 Berlin, Germany", 
      "@type": "Person", 
      "name": "van de Krol, Roel"
    }, 
    {
      "@id": "https://orcid.org/0000-0002-9671-8628", 
      "affiliation": "Institute of Fluid Dynamics, Helmholtz-Zentrum Dresden-Rossendorf, 01328 Dresden, Germany", 
      "@type": "Person", 
      "name": "Eckert, Kerstin"
    }
  ], 
  "identifier": "https://doi.org/10.14278/rodare.4547", 
  "@id": "https://doi.org/10.14278/rodare.4547", 
  "version": "1"
}
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