March 27, 2026 Dataset Open Access

Rox, Hannes; Liang, Feng; Baumann, Robert; Marzec, Mateusz M.; Sokołowski, Krystian; Yang, Xuegeng; Lasagni, Andrés F.; van de Krol, Roel; Eckert, Kerstin

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{
  "title": "Data publication: Bubbles under pressure and their impact on electrode potentials during alkaline water electrolysis", 
  "DOI": "10.14278/rodare.4547", 
  "language": "eng", 
  "issued": {
    "date-parts": [
      [
        2026, 
        3, 
        27
      ]
    ]
  }, 
  "version": "1", 
  "note": "This project is supported by the Federal State of Saxony in terms of the \"European Regional Development Fund\" (H2-EPF-HZDR), the Helmholtz Association Innovation pool project \"Solar Hydrogen\", the Hydrogen Lab of the School of Engineering of TU Dresden, and BMBF (project ALKALIMIT, grant no. 03SF0731A).", 
  "abstract": "<p>Understanding how bubbles influence the efficiency of water electrolysis is crucial to achieve economically competitive hydrogen, generated by renewable energy sources, such as wind and solar power. Water electrolysis is typically performed at high pressures to &nbsp;lower the cost of the energy-intensive mechanical compression required for the produced hydrogen. Thus, a better understanding of how absolute pressure affects electrochemical performance and bubble size is necessary.&nbsp; This data set compares four laser-structured Ni electrodes with different spatial periods (<strong>&Lambda; = 30, 40, 60, and 100 &mu;m</strong>) at a constant depth of <strong>&asymp;&nbsp;7 &mu;m</strong>. The comparison is made in terms of electrode potential, detached bubble size, and the number of nucleation sites. The applied current density was varied between<em> </em><strong><em>j </em>= -25, -50, and -100 mA/cm&sup2;</strong>, and the absolute cell pressure was varied between <strong><em>p</em> = 1, 2, 4, and 6 bar</strong>. The electrolyte used was <strong>1 M KOH</strong>. All experiments were carried out at a constant temperature of <strong>T = 293 K</strong>.</p>\n\n<p><strong>A.) Description of <em>Data.zip</em>:</strong></p>\n\n<p>An overview of all performed experiments is given in the file <strong><em>Summary.csv</em></strong>. The data is analyzed as described in the corresponding journal publication <em><strong>Bubbles under pressure and their impact on electrode potentials during<br>\nalkaline water electrolysis</strong></em>. Each data set is stored in a .hdf5-file, with the relevant metadata incorporated into the attributes assigned to the groups/datasets within the .hdf5-file. The data files are structured in groups as follows:</p>\n\n<ul>\n\t<li>Electrochemical Measurement Data\n\t<ul>\n\t\t<li>Galvanostatic Measurement Data</li>\n\t</ul>\n\t</li>\n\t<li>Results\n\t<ul>\n\t\t<li>Detected Bubbles Frontview</li>\n\t</ul>\n\t</li>\n\t<li><em>Frontview Raw Images (only for <strong>LS_P_01.hdf5</strong>)</em></li>\n</ul>\n\n<p>With the exception of a single comprehensive data set comprising unprocessed images (<strong>LS_P</strong><strong>_01.hdf5</strong>), the remaining raw images from all performed measurements can be made available upon request.</p>\n\n<p><strong>B.) Description of <em>Videos.zip</em>:</strong></p>\n\n<p>Example videos of non-structured and laser-structured electrodes at a current density of <strong>-100 mA/cm&sup2;</strong> are provided. The characteristic videos provided are named according to the following scheme:</p>\n\n<ul>\n\t<li><em>SpatialPeriod_Pressure_CurrentDensity</em></li>\n\t<li><em>E.g.: </em>100&mu;m_6bar_-100mAcm-2</li>\n</ul>", 
  "type": "dataset", 
  "id": "4547", 
  "publisher": "Rodare", 
  "author": [
    {
      "family": "Rox, Hannes"
    }, 
    {
      "family": "Liang, Feng"
    }, 
    {
      "family": "Baumann, Robert"
    }, 
    {
      "family": "Marzec, Mateusz M."
    }, 
    {
      "family": "Soko\u0142owski, Krystian"
    }, 
    {
      "family": "Yang, Xuegeng"
    }, 
    {
      "family": "Lasagni, Andr\u00e9s F."
    }, 
    {
      "family": "van de Krol, Roel"
    }, 
    {
      "family": "Eckert, Kerstin"
    }
  ]
}