August 27, 2020 Dataset Open Access

Fichter, Sebastian; Kaufmann, Sebastian; Kaden, Peter; Brunner, Tobias S.; Stumpf, Thorsten; Roesky, Peter W.; März, Juliane

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    "title": "Data for: Enantiomerically pure Tetravalent Neptunium Amidinates: Synthesis and Characterization", 
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        "name": "Fichter, Sebastian", 
        "orcid": "0000-0002-0723-7778"
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        "name": "Kaufmann, Sebastian", 
        "affiliation": "Karlsruhe Institute of Technology"
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      {
        "name": "Kaden, Peter", 
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        "affiliation": "Karlsruhe Institute of Technology"
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        "affiliation": "Karlsruhe Institute of Technology", 
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    "description": "<p>The synthesis of a tetravalent neptunium amidinate [NpCl((S)\u2010PEBA)3] (1) ((S)\u2010PEBA=(S,S)\u2010N,N&prime;\u2010bis\u2010(1\u2010phenylethyl)\u2010benzamidinate) is reported. This complex represents the first structurally characterized enantiopure transuranic compound. Reactivity studies with halide/pseudohalides yielding [NpX((S)\u2010PEBA)3] (X=F (2), Br (3), N3 (4)) have shown that the chirality\u2010at\u2010metal is preserved for all compounds in the solid state. Furthermore, they represent an unprecedented example of a structurally characterized metal&ndash;organic Np complex featuring a Np&minus;Br (3) bond. In addition, 4 is the only reported tetravalent transuranic azide. All compounds were additionally characterized in solution using para\u2010magnetic NMR spectroscopy showing an expected C3\u2010symmetry at low temperatures.</p>", 
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