May 12, 2025 Dataset Open Access

Raza, Asif; Javan Nikkhah, Sousa; Croitor, Lilia; Elsherif, Ahmed Gamal Attallah; Hirschmann, Eric; Vandiche, Matthias; Mukherjee, Soumya

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    <subfield code="a">&lt;p&gt;A nanopore engineering approach enhances acetylene (C2H2) over carbon dioxide (CO2) selectivity in ionic ultramicroporous polymers (IUPs), an understudied class of sorbents. Extending the cationic arm of a prototypical IUP nearly doubles its C2H2/CO2 selectivity from 4.9 to 8.5 (at 298 K, 1 bar), underpinned by further observations from dynamic separation experiments and bespoke computational insights.&lt;/p&gt;</subfield>
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